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Free Gibbs Enthalpies and pe Values for Silver

Unified Reducity of Ag+/Ag
Solvent S

ΔsolvG°(Ag+, S)

/ kJ mol−1

pMabs

 

pK'e = pe°abs

(Ag+/Ag, S)

E°abs

(Ag+/Ag, S) / V

E°S / V

H2O −489.10 85.69 85.77 5.07 0.80
MeCN −512.30 89.75 81.70 4.83 0.08
DMSO −523.90 91.78 79.67 4.71 0.64
NH3 −589.10 103.21 68.25 4.04 0.77
DCE a −423.70 74.23 97.23 5.75 −1.06
EMIM Br b −598,10 104.78 66.67 3.94 −0.36
MeOH −482.50 84.53 86.93 5.14 0.76
EtOH −484.20 84.83 86.63 5.12 0.73
1-PrOH −488.10 85.51 85.94 5.08 0.72
EG −488.10 85.51 85.94 5.08 0.76
DMF −509.90 89.33 82.13 4.86 0.73
PC −470.30 82.39 89.06 5.27 0.48
NMPy −515.10 90.24 81.21 4.80 0.79
MeNO2 −468.10 82.01 89.45 5.29 0.03
Py −546.10 95.67 75.78 4.48 0.50
HMPT −533.10 93.39 78.06 4.62 −0.07
If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] ; a) calculated with rCCC-model [2]; b) calculated with COSMO-RS

 

[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622. [2] D. Himmel, S. K. Goll, I. Leito, I. Krossing, Chem. Eur. J. 2011, 17, 5808.

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