Free Gibbs Enthalpies and pe Values for Chlorine
Solvent S | ΔsolvG°(Cl2, S) / kJ mol−1 | pMabs
| pK'e = pe°abs (Cl2/Cl−, S) | E°abs (Cl2/Cl−, S) / V | E°S / V |
---|---|---|---|---|---|
H2O | −304,00 | 53,26 | 95.26 | 5.64 | 1.36 |
MeCN | −261.90 | 45.88 | 87.92 | 5.20 | 0.44 |
DMSO | −263.70 | 46.20 | 88.23 | 5.22 | 1.15 |
NH3 | −261.00 | 45.73 | 87.76 | 5.19 | 1.92 |
DCE | −252.00 | 44.15 | 86.18 | 5.10 | −1.71 |
MeOH | −290.80 | 50.95 | 92.98 | 5.50 | 1.12 |
EtOH | −283.80 | 49.72 | 91.76 | 5.43 | 1.04 |
1-PrOH | −278.00 | 48.70 | 90.74 | 5.37 | 1.00 |
1-BuOH | −275.00 | 48.18 | 90.21 | 5.34 | 1.03 |
EG | −295.00 | 51.68 | 93.72 | 5.54 | 1.22 |
DMF | −255.70 | 44.80 | 86.83 | 5.14 | 1.01 |
PC | −264.20 | 46.29 | 88.32 | 5.23 | 0.43 |
NMPy | −253.00 | 44.32 | 86.36 | 5.11 | 1.09 |
MeNO2 | −266.30 | 46.65 | 88.69 | 5.25 | −0.01 |
PhNO2 | −269.00 | 47.13 | 89.16 | 5.27 | 0.66 |
Py | −270.00 | 47.30 | 89.34 | 5.29 | 1.30 |
HMPT | −246.00 | 43.10 | 85.13 | 5.04 | 0.35 |
If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] |
[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.