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Free Gibbs Enthalpies and pe Values for Chlorine

Unified Reducity of Cl2/Cl
Solvent S

ΔsolvG°(Cl2, S)

/ kJ mol−1

pMabs

 

pK'e = pe°abs

(Cl2/Cl, S)

E°abs

(Cl2/Cl, S) / V

E°S / V

H2O −304,00 53,26 95.26 5.64 1.36
MeCN −261.90 45.88 87.92 5.20 0.44
DMSO −263.70 46.20 88.23 5.22 1.15
NH3 −261.00 45.73 87.76 5.19 1.92
DCE −252.00 44.15 86.18 5.10 −1.71
MeOH −290.80 50.95 92.98 5.50 1.12
EtOH −283.80 49.72 91.76 5.43 1.04
1-PrOH −278.00 48.70 90.74 5.371.00
1-BuOH −275.00 48.18 90.21 5.34 1.03
EG −295.00 51.68 93.72 5.54 1.22
DMF −255.70 44.80 86.83 5.14 1.01
PC −264.20 46.29 88.32 5.23 0.43
NMPy −253.00 44.32 86.36 5.11 1.09
MeNO2 −266.30 46.65 88.69 5.25 −0.01
PhNO2 −269.00 47.13 89.16 5.27 0.66
Py −270.00 47.30 89.34 5.29 1.30
HMPT −246.00 43.10 85.13 5.04 0.35
If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] 

 

[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.

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