Own Values (ILSB Method)

All values are given in V. The green shaded values are reference values, the yellow shaded values werde determined with cell I, and the blue shaded values with cell II, the light blue shaded values can be derived from them. The light yellow values were obtained with values from cell I and values of measurements in the solvent S between the redox systems Ag⁺/Ag vs H⁺/H₂ or Ag⁺/Ag vs Fc⁺/Fc or additionally Fc⁺/Fc vs H⁺/H₂ from literature (see below).

Ag│AgCi (c, S₂) │ [N₂₂₂₅][NTf₂] │ AgCi (yc, S₁)│Ag                                 cell I

Ag│AgCl│CiCl (c, S₂)│[N₂₂₂₅][NTf₂]│CiCl (yc, S₁)│AgCl│Ag                   cell II

Ci is an appropriate counterion. [N₂₂₂₅][NTf₂] is the pure ionic liquid used in the salt bridge. For details see: 1

A. Ermantraut, V. Radtke, N. Gebel, D. Himmel, T. Koslowski, I. Leito, I. Krossing, Angew. Chem. Int. Ed. 2018, 57, 2348.

V. Radtke, N. Gebel, D. Priester, A. Ermantraut, M. Bäuerle, D. Himmel, R. Stroh, T. Koslowski, I. Leito, I. Krossing, Chem. Eur. J. 2022, e202200509.

V. Radtke, D. Priester, A. Heering, C. Müller, T. Koslowski, I. Leito, I. Krossing, Chem. Eur. J. 2023, 29, e202300609.

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