Free Gibbs Enthalpies and pe Values for Silver
| Solvent S | ΔsolvG°(Ag+, S) / kJ mol−1 | pMabs
| pK'e = pe°abs (Ag+/Ag, S) | E°abs (Ag+/Ag, S) / V | E°S / V |
|---|---|---|---|---|---|
| H2O | −489.10 | 85.69 | 85.77 | 5.07 | 0.80 |
| MeCN | −512.30 | 89.75 | 81.70 | 4.83 | 0.08 |
| DMSO | −523.90 | 91.78 | 79.67 | 4.71 | 0.64 |
| NH3 | −589.10 | 103.21 | 68.25 | 4.04 | 0.77 |
| DCE a | −423.70 | 74.23 | 97.23 | 5.75 | −1.06 |
| EMIM Br b | −598,10 | 104.78 | 66.67 | 3.94 | −0.36 |
| MeOH | −482.50 | 84.53 | 86.93 | 5.14 | 0.76 |
| EtOH | −484.20 | 84.83 | 86.63 | 5.12 | 0.73 |
| 1-PrOH | −488.10 | 85.51 | 85.94 | 5.08 | 0.72 |
| EG | −488.10 | 85.51 | 85.94 | 5.08 | 0.76 |
| DMF | −509.90 | 89.33 | 82.13 | 4.86 | 0.73 |
| PC | −470.30 | 82.39 | 89.06 | 5.27 | 0.48 |
| NMPy | −515.10 | 90.24 | 81.21 | 4.80 | 0.79 |
| MeNO2 | −468.10 | 82.01 | 89.45 | 5.29 | 0.03 |
| Py | −546.10 | 95.67 | 75.78 | 4.48 | 0.50 |
| HMPT | −533.10 | 93.39 | 78.06 | 4.62 | −0.07 |
| If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] ; a) calculated with rCCC-model [2]; b) calculated with COSMO-RS |
[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622. [2] D. Himmel, S. K. Goll, I. Leito, I. Krossing, Chem. Eur. J. 2011, 17, 5808.