Free Gibbs Enthalpies and pe Values for Fluorine
| Solvent S | ΔsolvG°(F2, S) / kJ mol−1 | pMabs
| pK'e = pe°abs (F2/F−, S) | E°abs (F2/F−, S) / Vf | E°S / V |
|---|---|---|---|---|---|
| H2O | −429.00 | 75.16 | 121.03 | 7.16 | 2.88 |
| MeCN | −358.00 | 62.72 | 108.59 | 6.42 | 1.67 |
| DCE | −364.00 | 63.77 | 109.65 | 6.49 | −0.32 |
| MeOH | −413.00 | 72.35 | 118.23 | 6.99 | 2.61 |
| DMF | −378.00 | 66.22 | 112.10 | 6.63 | 2.51 |
| PC | −373.00 | 65.35 | 111.22 | 6.58 | 1.79 |
| PhNO2 | −385.00 | 67.45 | 113.32 | 6.70 | 2.09 |
| If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] |
[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.