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Free Gibbs Enthalpies and pe Values for Rubidium

 

Unified Reducity of Rb+/Rb
Solvent S

ΔsolvG°(Rb+, S)

/ kJ mol−1

pMabs

 

pK'e = pe°abs

(Rb+/Rb, S)

E°abs

(Rb+/Rb, S) / V

E°S / V

H2O −329.00 57.64 22.56 1.33 −2.94
MeCN −322.70 56.53 23.67 1.40 −3.36
DMSO −339.40 59.46 20.74 1.23 −2.85
NH3 −342.00 59.92 20.29 1.20 −2.07
DCE −304.00 53.26 26.94 1.59 −5.22
MeOH −319.40 55.96 24.24 1.43 −2.95
EtOH −313.00 54.83 25.37 1.50 −2.89
1-PrOH −310.00 54.31 25.89 1.53 −2.84
1-BuOH −306.00 53.61 26.59 1.57 −2.73
DMF −338.70 59.34 20.86 1.23 −2.89
PC −330.00 57.81 22.39 1.32 −3.47
NMPy −337.00 59.04 21.16 1.25 −2.76
MeNO2 −318.00 55.71 24.49 1.45 −3.81
PhNO2 −310.00 54.31 25.89 1.53 −3.09
Py −316.00 55.36 24.84 1.47 −2.52
HMPT −339.00 59.39 20.81 1.23 −3.46
If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] 

 

[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.

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