Free Gibbs Enthalpies and pe Values for Lithium
| Solvent S | ΔsolvG°(Li+, S) / kJ mol−1 | pMabs
| pK'e = pe°abs (Li+/Li, S) | E°abs (Li+/Li, S) / V | E°S / V |
|---|---|---|---|---|---|
| H2O | −529.40 | 92.75 | 20.86 | 1.23 | −3.04 |
| MeCN | −504.40 | 88.37 | 25.24 | 1.49 | −3.26 |
| DMSO | −544.40 | 95.37 | 18.23 | 1.08 | −3.00 |
| NH3 | −564.40 | 98.88 | 14.73 | 0.87 | −2.40 |
| MeOH | −525.00 | 91.98 | 21.63 | 1.28 | −3.10 |
| EtOH | −518.40 | 90.82 | 22.79 | 1.35 | −3.04 |
| 1-PrOH | −518.40 | 90.82 | 22.79 | 1.35 | −3.02 |
| EG | −529.40 | 92.75 | 20.86 | 1.23 | −3.09 |
| DMF | −539.40 | 94.50 | 19.11 | 1.13 | −3.00 |
| PC | −505.60 | 88.58 | 25.03 | 1.48 | −3.31 |
| NMPy | −564.40 | 98.88 | 14.73 | 0.87 | −3.14 |
| MeNO2 | −481.40 | 84.34 | 29.27 | 1.73 | −3.53 |
| PhNO2 | −491.40 | 86.09 | 27.52 | 1.63 | −2.99 |
| If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] |
[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.