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Free Gibbs Enthalpies and pe Values for Sodium

 

Unified Reducity of Na+/Na
Solvent S

ΔsolvG°(Na+, S)

/ kJ mol−1

pMabs

 

pK'e = pe°abs

(Na+/Na, S)

E°abs

(Na+/Na, S) / V

E°S / V

H2O −423.70 74.23 26.42 1.56 −2.71
MeCN −408.60 71.58 29.07 1.72 −3.04
DMSO −437.10 76.58 24.07 1.42 −2.65
NH3 −440.70 77.21 23.44 1.39 −1.88
DCE −398.70 69.85 30.80 1.82 −4.99
MeOH −415.50 72.79 27.86 1.65 −2.74
EtOH −409.70 71.78 28.87 1.71 −2.68
1-PrOH −406.70 71.25 29.40 1.74 −2.63
1-BuOH −404.70 70.90 29.75 1.76 −2.55
EG −425.70 74.58 26.07 1.54 −2.78
DMF −433.30 75.91 24.74 1.46 −2.66
PC −409.10 71.67 28.98 1.71 −3.08
NMPy −438.70 76.86 23.79 1.41 −2.61
MeNO2 −392.10 68.69 31.96 1.89 −3.37
PhNO2 −387.70 67.92 32.73 1.94 −2.68
Py −407.70 71.43 29.22 1.73 −2.26
HMPT −440.70 77.21 23.44 1.39 −3.30
If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] 

 

[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.

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