Free Gibbs Enthalpies and pe Values for Sodium
| Solvent S | ΔsolvG°(Na+, S) / kJ mol−1 | pMabs
| pK'e = pe°abs (Na+/Na, S) | E°abs (Na+/Na, S) / V | E°S / V |
|---|---|---|---|---|---|
| H2O | −423.70 | 74.23 | 26.42 | 1.56 | −2.71 |
| MeCN | −408.60 | 71.58 | 29.07 | 1.72 | −3.04 |
| DMSO | −437.10 | 76.58 | 24.07 | 1.42 | −2.65 |
| NH3 | −440.70 | 77.21 | 23.44 | 1.39 | −1.88 |
| DCE | −398.70 | 69.85 | 30.80 | 1.82 | −4.99 |
| MeOH | −415.50 | 72.79 | 27.86 | 1.65 | −2.74 |
| EtOH | −409.70 | 71.78 | 28.87 | 1.71 | −2.68 |
| 1-PrOH | −406.70 | 71.25 | 29.40 | 1.74 | −2.63 |
| 1-BuOH | −404.70 | 70.90 | 29.75 | 1.76 | −2.55 |
| EG | −425.70 | 74.58 | 26.07 | 1.54 | −2.78 |
| DMF | −433.30 | 75.91 | 24.74 | 1.46 | −2.66 |
| PC | −409.10 | 71.67 | 28.98 | 1.71 | −3.08 |
| NMPy | −438.70 | 76.86 | 23.79 | 1.41 | −2.61 |
| MeNO2 | −392.10 | 68.69 | 31.96 | 1.89 | −3.37 |
| PhNO2 | −387.70 | 67.92 | 32.73 | 1.94 | −2.68 |
| Py | −407.70 | 71.43 | 29.22 | 1.73 | −2.26 |
| HMPT | −440.70 | 77.21 | 23.44 | 1.39 | −3.30 |
| If not otherwise stated values for ΔtrG°(H+, H2O → S) according to Marcus et al. [1] |
[1] Y. Marcus, M. J. Kamlet, R. W. Taft, J. Phys. Chem. 1988, 92, 3613-3622.